Using water as the hydrogen source for electrocatalytic transfer hydrogen storage

Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles.

A series of water-soluble molecular cobalt complexes of tetraazamacrocyclic ligands are reported for the electrocatalytic production of H(2) from pH 2.2 aqueous solutions. The comparative data reported for this family of complexes shed light on their relative efficiencies for hydrogen evolution in water. Rotating disk electrode voltammetry data are presented for each of the complexes discussed,...

PERFORMANCE OF AB, ALLOYS FOR HYDROGEN STORAGE AND HYDRIDE ELECTRODES

Two types of hydride electxodes are potential candidates to replace the Cd elecsode in NilCd batteries, One is of the A type where A is a rare earth metal or mixture thereof, and B is the transition metal. The other is commonly referred to as A type. A , type alloys with partial substitution of the B element in A type hydride material (Ovonic) with Co, Mn, Al, and Fe were studied (A compo...

Nanoscale Magnesium as a Hydrogen Storage Material

Electrocatalytic Activity of the Ni57.3Co42.7 Alloy for the Hydrogen Evolution

The hydrogen evolution reaction (HER) on Ni57.3Co42.7 alloy and its main components, polycrystalline nickel and cobalt was investigated in 1.0 mol L–1 NaOH solution at 20 °C using cyclic voltammetry, pseudo-steady-state linear polarization and electrochemical impedance spectroscopy methods. The purpose of investigation was to evaluate the effect of cobalt on the intrinsic catalytic activity of ...

Electrocatalytic hydrogen evolution using amorphous tungsten phosphide nanoparticles.

Amorphous tungsten phosphide (WP), which has been synthesized as colloidal nanoparticles with an average diameter of 3 nm, has been identified as a new electrocatalyst for the hydrogen-evolution reaction (HER) in acidic aqueous solutions. WP/Ti electrodes produced current densities of -10 mA cm(-2) and -20 mA cm(-2) at overpotentials of only -120 mV and -140 mV, respectively, in 0.50 M H2SO4(aq).